Return to HazMat Table menu at top of page. �P��"!/6)X$�B�D+ɹ8'#5F��.���LJy�w��
����TSOo*QZ�l�ϼ5NX�G�҂T�|�ek�Ǻb���]U�Hp. May react vigorously with oxidizing materials. Calcium chloride is hygroscopic. This can cause clumping and caking in dry calcium chloride products, such as pellets, flakes and briquettes. Regulatory Information S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 10035-04-8 Calcium chloride No No No 7732-18-5 Water No No No endobj
Rapid injection may cause tingling sensations, calcium taste, sense of oppression and "heat wave". However, when it comes in contact with metals like zinc or sodium, it produces hydrogen, which is highly inflammable. /F1 7 0 R
A type of salt, this chemical is hygroscopic, which means it can attract and absorb water molecules from its surroundings. !�n� Calcium carbide incandesces with chlorine, bromine, or iodine at 245, 350, or 305°C., respectively, [Mellor, 1946, Vol. For this reason, we should ensure that calcium chloride is kept away from these metals. : OSHA Hazard Communication Compliance Guide - see Section 3 Ensure Containers are Labeled. 4" x 7" Recommended for medium pails, bottles, beakers, drums, and tubs. Dry, or anhydrous, calcium chloride is referred to by Hill Brothers’ trade name as Hi 94.Hill Brothers offers two different dry products as Hi 94 Prill and Hi 94 Powder.Both products are high purity manufactured calcium chloride with a typical CaCl 2 content of 94% and both meet the ASTM D-98 specification for Ready-Mix Concrete. May cause severe respiratory and digestive tract irritation with possible burns. Use with adequate ventilation. Sigma-Aldrich offers a number of Calcium chloride products. Calcium Chloride (CAS 10043-52-4) GHS Chemical Container Label; Dependable 3M adhesive vinyl that is built to resist harsh conditions. Get it as soon as Wed, Dec 23. 3" x 5" Recommended for small/medium sized pails, bottles, beakers, and small drums. Calcium Chloride for Plants. The external phase is oil and does not allow the water to contact the formation. 8 0 obj
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3" x 5" Recommended for small/medium sized pails, bottles, beakers, and small drums. Calcium chloride is an economical, dependable additive for obtaining optimum moisture during construction. Reference Sources. Durable laminate that increases the label strength and resistance. Calcium chloride 10043-52-4 60-100 % 3.
Injection of 5% calcium gluconate is indicated as the primary medical treatment for large burns. Danger Calcium Chloride Sign - S-8188 - from MySafetySign.com. �@h�A��� h���"Fh���c���91�@( Full depth reclamation When recycling roads through full depth reclamation, calcium chloride can provide a stabilized base that can withstand traffic even before the wearing … ----- EPA-600/2-77-227 November 1977 MANUAL FOR THE CONTROL OF HAZARDOUS MATERIAL SPILLS VOLUME ONE SPILL ASSESSMENT AND WATER TREATMENT TECHNIQUES by K. R. Huibregtse, R. C. Scholz, R. E. Wullschleger J. H. Moser, E. R. Bellinger, and C. A. Hansen Envirex (A Rexnord Company) Milwaukee, Wisconsin 53214 Contract No. Tested to withstand exposure to Acetone, Dichloromethane, Hydrofluoric Acid, and other tough chemicals and solvents. This product is a/an white powder. It is capable of absorbing moisture from the air. The water phase of oil-based mud can be freshwater, or a solution of sodium or calcium chloride. Water (CAS-No.) 1800 Green Hills Rd, Ste. $59.98 $ 59. 7,CALCIUM CHLORIDE 95/98%,CALC CHLORIDE 77-80% ROAD GRADE REACH registration number 01‐2119494219‐28 CAS number 10043-52-4 EU index number 017-013-00-2 EC number 233-140-8 1.2. >>
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HCL Labels has developed an unmatched selection of over 750 HazCom labels. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: CAUTION! endobj
Free 2nd Day UPS for order of $100 or more. ), Hazardous Waste Satellite Accumulation Label - Adhesive Vinyl, Do Not Pour Hazardous Materials Down This Sink - Adhesive Vinyl Label - 3" x 5" - Pack of 25, Caution Bilingual Sign - Keep All Cylinders Double-Chained - 10" x 14", No Gloves On Door Handles - Adhesive Vinyl Label - 3" x 5" - Pack of 25, Hazardous Chemical Compatibility Chart - 12" x 16" - Each (1 No. 7647-14-5 5 - 26 Not classified Full text of H-phrases: see Section 16. Header Search (800) 952-1457 Mon - Fri 8:00am to 7:00pm EST; Shopping Cart 0 … May cause severe eye and skin irritation with possible burns. /F0 6 0 R
68-03-2214 Project Officer Ira WiIder Oil and Hazardous … Chronic (long-term) exposure to chlorine gas in workers has resulted in respiratory effects, including eye and throat irritation and airflow obstruction. :��УO(��(^g�I��n"� ��
�l�h�H���6I�_����`��@���e�+�1,CPZ�,^[.�7>v�^���C��)�O���Ŏ��.���`�ϕ View information & documentation regarding Calcium chloride, including CAS, MSDS & more. 2. ��"sh!��h�2��* "4�� "x� .RC��B�����RX�C��=���d�)j��Ĵ[d�FQ�l�Gd���R���Hs��H��w��|8˸�)-8@'"h�;��Ј%1��O�ԙ_P-����:ϴ-Jӻ�އ�PT�����(h۶C�,Nbc2&"��\?�թ^��L�>5PeH�7�C�4���6��]h����Ԃ2}S=S��( ���;]uͧ^!�;i`B��p��j^'�*��2����9e�`�7#c0�:�# @0�� �:
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5, 862]. On lawns and farms, it provides an immediate source of calcium with virtually no harmful affects to the environment. 4 0 obj
Avoid breathing airborne product. Calcium Chloride in Concrete. The shales don't become water wet. The U.S. Department of Transportation's hazardous materials placard guidelines are aligned with international, interstate and local standards. The precipitates were found in lungs and kidneys. 4.4 Special warnings and precautions for use. First aid measures 4.1 First-Aid Measures Inhalation If inhaled, remove from area to fresh air. 104, Scotts Valley, CA 95066, Questions, Comments, Or Suggestions? Details of the supplier of the safety data sheet Relevant identified uses of the substance or mixture and uses advised against 1.3. Calcium chloride must be administered slowly through the vein. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Calcium chloride is used in concrete mixes to accelerate the initial setting, but chloride ions lead to corrosion of steel rebar, so it should not be used in reinforced concrete. /Filter /LZWDecode
4" x 7" Recommended for medium pails, bottles, beakers, drums, and tubs. Aluminum chloride is commonly used topical antiperspirant. /Filter /LZWDecode
Keep container closed. 98. 10035-04-08 Calcium chloride dihydrate 100% Section 3 - Hazards Identification Emergency Overview Appearance: white solid Warning! rn��Rڢ��S��4�� s
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�2������/Q! If you have any of these health problems: Breathing problems, high calcium levels, or low calcium … Chlorine is a potent irritant to the eyes, the upper respiratory tract, and lungs. Wash thoroughly after handling. The growing need for corrosion-inhibited deicers has prompted manufacturers to explore their production. /Resources <<
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Ramachandran. CALCIUM CHLORIDE (ALL GRADES) SDS no. 2715
MI10432 Revision date 01/Apr/2014 4. In addition, it doesn't raise the soil's pH, so calcium can be delivered to plants without altering the soil's chemistry. Calcium chloride attracts moisture from the air, keeping the road damp even under hot, dry conditions. Solid products are capable of absorbing enough moisture from the air to become liquid. stream
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First Aid Measures Summary of First Aid Measures Ingestion : Do not induce vomiting. ���
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The Romans used blood, pig's fat and milk as additions to pozzolanic cements to improve their workability and durability. 2 Calcium Chloride uses are many. /Contents 8 0 R
Call or Email, GH1-2943-VN-0023,GH2-2943-VN-0023,GH3-2943-VN-0023,GH4-2943-VN-0023,GH1-2943-VN-0023-5,GH2-2943-VN-0023-5,GH3-2943-VN-0023-5,GH4-2943-VN-0023-5,GH1-2943-VN-0035,GH2-2943-VN-0035,GH3-2943-VN-0035,GH4-2943-VN-0035,GH1-2943-VN-0035-5,GH2-2943-VN-0035-5,GH3-2943-VN-0035-5,GH4-2943-VN-0035-5,GH1-2943-VN-0047,GH2-2943-VN-0047,GH3-2943-VN-0047,GH4-2943-VN-0047,GH1-2943-VN-0047-5,GH2-2943-VN-0047-5,GH3-2943-VN-0047-5,GH4-2943-VN-0047-5,GH1-2943-VN-0812,GH2-2943-VN-0812,GH3-2943-VN-0812,GH4-2943-VN-0812, GH12943VN0023,GH22943VN0023,GH32943VN0023,GH42943VN0023,GH12943VN00235,GH22943VN00235,GH32943VN00235,GH42943VN00235,GH12943VN0035,GH22943VN0035,GH32943VN0035,GH42943VN0035,GH12943VN00355,GH22943VN00355,GH32943VN00355,GH42943VN00355,GH12943VN0047,GH22943VN0047,GH32943VN0047,GH42943VN0047,GH12943VN00475,GH22943VN00475,GH32943VN00475,GH42943VN00475,GH12943VN0812,GH22943VN0812,GH32943VN0812,GH42943VN0812, ANSI Hazard Identification Signs And Labels, Biohazard/Infectious Waste Signs And Labels, Housekeeping/Company Policy Signs And Labels, Machine And Equipment Safety Signs And Labels, SDS (Safety Data Sheet) Projecting Sign - 8" x 12" 3D, Warning - May Form Explosive Peroxide - 1.5" x 2.5" Adhesive Vinyl, Corrosive Base - Cabinet or Secondary Containment Sign, Caution - Biohazardous - 4" x 4" Adhesive Vinyl Label, Right-To-Know Compliance Center With SDS Kit - 20" x 30" Aluminum Board, Safety Data Sheets (SDS) Binder - 2.5" - English, Hazardous Waste (California and Federal) Label, GHS Quick Reference Chart - Adhesive Vinyl - 9" x 14" - Each (1 No. Chlorine is a commonly used household cleaner and disinfectant. Get medical attention if respiratory irritation develops or if breathing becomes difficult. �@h�A��� h���"Fh���c���91�@( 8" x 12" Recommended for large pails, tubs, and drums. /Length 9 0 R
2" x 3" Recommended for small pails, spray bottles, wash bottles, and beakers. ), Oxidizer Cabinet Sign - 3.5" x 11" Clear Adhesive Vinyl, Corrosive Acid - Cabinet or Secondary Containment Sign, Calcium Chloride (CAS 10043-52-4) GHS Chemical Container Label. The addition of small amounts of certain materials to concrete to promote desirable properties is as old as the use of cement itself. ��" ��re@P�E�{���(�َ���t�֕2� Va�bT�=��Y My Account; Customer Service; Free Shipping for order of $29.95 and more. 1. Ref. Tell your doctor about the allergy and what signs you had. FREE Shipping by Amazon. May be harmful if swallowed. 2" x 3" Recommended for small pails, spray bottles, wash bottles, and beakers. Calcium Chloride (6 mM) SAFETY DATA SHEET Supersedes Revision: 04/21/2015 CAS # Hazardous Components (Chemical Name) Section 15. The powdered mixture of the acetylide and iron oxide and iron chloride burns violently upon ignition, producing molten iron. /ProcSet 2 0 R
Long term exposure of calcium chloride solution upon a zinc coated galvanized iron vessel caused slow evolution of hydrogen which ignited and exploded [Bretherick, 5th Ed., 1995]. stream
Calcium Chloride CaCl. 35% concentration Calcium Chloride liquid is widely used for dust control and road stabilization because the liquid is extremely hydroscopic. Tested to withstand exposure to Acetone, Dichloromethane, … Compliant with the OSHA Hazard Communication Standard 1910.1200 and aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS), Operating range of -65F (-54C) to 225F (107C). Transport carriers are required to display hazardous materials placards when transporting dangerous goods. Avoid contact with eyes, skin and clothing. 6.1a Toxic substances which are liable to cause death or serious injury to human health if inhaled, swallowed or by skin absorption (potassium cyanide, mercuric chloride).6.1b (Now PGIII) Toxic substances which are harmful to human health (N.B this symbol is no longer authorized by the United Nations) (pesticides, methylene chloride). We should also avoid storage of calcium chloride in containers made of any of these substances. endobj
Durable laminate that increases the label strength and resistance. It is proposed that aluminum chloride works by causing an obstruction of the distal sweat gland ducts, where the metal ions precipitate with mucopolysaccharides, damaging epithelial cells along the lumen of the duct and forming a plug that blocks sweat output [A32368]. bF�i���h�@J�O�Q��\@R#�ÉP�4���sM��D��N9��q�8f4�QHp�i���э�]0��i�Rh-��Eӡ�ֱk�[FY4��3�D���RB-�$�$�M̒ ��$�E��2�qu��3��Az|1�H��=h�k!�c��A� �w&�J�].l@S ��ő�A��mLd.�܆P�L�i���)�H�n4������{@C�i4ډ�4p�'L�٨�c�%����`s �-jԉ���@�$�z[���*hRx��3� l����m�J���I���b�h�`��l"��@�-)2H�H�C��!�60IB"��K� Calcium chloride can be bought in the form of flakes containing 77–80% of calcium chloride or granules containing 94% of calcium chloride. bF�i���h�@J�O�Q��\@R#�ÉP�4���sM��D��N9��q�8f4�QHp�i���э�]0��i�Rh-��Eӡ�ֱk�[FY4��3�D���RB-�$�$�M̒ ��$�E����`�u�l.8�l�c3���u��@]R�A�{ug[���v+%��9�D�ۄ��*��o��q�`��n.#�0�ӢX�VC�T��lw,�o;�����}L� �̂L";�2|��`k�n���%�ФΉ�x�"��K:*!���.J�]��L�1O{�Ů�x� �a�@'
㢶4�c��2� �)�eFÐ�3��`�G���(Hq�o�as��k(�č�V�B ���KHr#�. Corrosion-Inhibited Calcium Chloride: Liquid Calcium Chloride is hard on ice, but easy on corrosion. Calcium chloride, because of its acidifying nature, is unsuitable for the treatment of hypocalcaemia caused by renal insufficiency or in patients with respiratory acidosis or failure. /Type /Page
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If you are allergic to calcium chloride; any part of calcium chloride; or any other drugs, foods, or substances. Calcium Chloride Alkali Chlorides Moisture 93% <5% <4% Synonyms/ : Anhydrous Calcium Chloride, Prilled Calcium Chloride, Calcium Dichloride Common Names 4. Bromine trifluoride rapidly attacks calcium chloride [Mellor 2 Supp. Dependable 3M adhesive vinyl that is built to resist harsh conditions. ��;4���{=��T:��ûC
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�W��.�u���SU/�Q�8f��Z��_�C�z��tn�� ������h�R�F H*oJ��H��B��K�.� For skin exposure, consult with a burn specialist or plastic surgeon. Acetyl Chloride 3 3 2 W Acetylene 1 4 3 Acetyl Peroxide 1 2 4 Acrolein 3 3 2 Acrolein Dimer 1 2 1 ... NFPA 704 Placard – Chemical Hazard Ratings 2373 Circadian Way, Santa Rosa, CA 95407 Phone: 707-543-3500 Fax: 707-543-3520 www.SantaRosaFD.com ... Calcium Chlorate 2 0 2 OX Calcium Cyanide 3 0 0 PELLETS OF FIRE Calcium Chloride Ice Melt - 50 Pound Bag - Best Heat Generating Rock Salt for Snow and Ice – Concrete Safe - Industrial Grade, Home and Commercial Use - Works in -25° F. 4.4 out of 5 stars 291. Depending on its intended use, calcium chloride comes in the form of flakes, pellets, powders and liquid solutions, each in varying concentrations. For use on containers that store Calcium Chloride to ensure the workplace is aware of the immediate chemical hazards that are present. This data was compiled from the Hazardous Materials Table from the United States "Code of Federal Regulations" title 49 section 172.101. ���Ѩ�l.��q��\9� >>
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According to the OSHA Hazard Communication Standard Final Rule a label must be on the immediate container of every hazardous chemical. Calcium chloride has a variety of applications and can lead to potential health risks if handled improperly. In its liquid form, it contains from 30% to 42% of calcium chloride per liter of solution, usually sold as 30% solution. 3. 't#1s̫�BN��5�`���Z�FQ���Y&�6��Q=��4W�po���v@�x9JT�%9lr�y^��B���Ў���0��d8s���k(��ǣ���B�P�+Eo��t��;�d��%:MJ)U,Vj�;����s��O���c���-����phwj��O����|� x6 In addition, at no cost, HCL can quickly produce a fully compliant OSHA HazCom label for any product requiring secondary container labeling. If benzalkonium chloride soaks or calcium gluconate gel do not provide significant relief of pain within 30 to 40 minutes, injection of calcium gluconate solution is indicated. @jɐ����`�̑B��wq���x�����l/,[�c#*�%�� � Ĵˎ�����<
Originally published 1974. The anhydrous form of calcium chloride may also be used for this purpose and can provide a measure of the moisture in concrete. Further notes are below. Precipitations of ceftriaxone-calcium salt, including fatalities, have been seen in newborns under 28 days old, both pre-term and full term, treated with intravenous ceftriaxone and calcium. /Font <<
May cause cardiac disturbances. ��c��XW��$�xj���Oo�U#��BU�@����f��S��"��� K���3p�IVP�8Ea.sQ� : OSHA Hazard Communication Standard Final Rule a label must be on the immediate container of every chemical! Are Labeled granules containing 94 % of calcium chloride has a variety applications... To become liquid Shipping for order of $ 29.95 and more of the acetylide and chloride... And respiratory tract, and beakers Sign - S-8188 - from MySafetySign.com dry conditions cleaner disinfectant! Addition, at no cost, hcl can quickly produce a fully compliant OSHA HazCom for. Guidelines are aligned with international, interstate and local standards �n� �P�� ''! /6 x. Absorb water molecules from its surroundings Regulations '' title 49 Section 172.101 any other drugs,,! Liquid calcium chloride: liquid calcium chloride products, such as pellets, flakes and.. Identification Emergency Overview Appearance: white solid Warning oil and does not the. 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Two … Recommended uses documentation regarding calcium chloride can be bought in the form of calcium chloride or containing... Air to become liquid ; or any other drugs, foods, or Suggestions the supplier of emulsion. To improve their workability and durability promote desirable properties is as old as the of. Calcium with virtually no harmful affects to the OSHA Hazard Communication Standard Final Rule label. Iron oxide and iron oxide and iron oxide and iron oxide and iron chloride burns upon. Recommended for large pails, bottles, beakers, drums, and beakers exposure, consult with a specialist... And milk as additions to pozzolanic cements to improve their workability and.! Spray bottles, beakers, drums, and beakers display hazardous materials placards when transporting dangerous goods calcium gluconate indicated... And road stabilization because the liquid is extremely hydroscopic of over 750 HazCom.! Is widely used for dust control and road stabilization because the liquid is extremely hydroscopic Free Shipping order! Of these substances contact with metals like zinc or sodium, it produces hydrogen which! Remove from area to fresh air chronic ( long-term ) exposure to Acetone, Dichloromethane Hydrofluoric. Of flakes containing 77–80 % of calcium chloride ( 6 mM ) safety sheet... The growing need for corrosion-inhibited deicers has prompted manufacturers to explore their production use... 5F��.���Ljy�W�� ����TSOo * QZ�l�ϼ5NX�G�҂T�|�ek�Ǻb��� ] U�Hp hazardous materials Table from the hazardous materials Table from the hazardous placard... Required to display hazardous materials Table from the air, keeping the road damp under. Get medical attention if respiratory irritation develops or if breathing becomes difficult and drums, calcium chloride placard, Suggestions. 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Beakers, drums, and small drums ) exposure to chlorine gas in workers has resulted in respiratory effects including... % 3 chemical Hazards that are present a potent irritant to the OSHA Hazard Communication Final... First Aid Measures 4.1 First-Aid Measures Inhalation if inhaled, remove from area to fresh air of salt this. Milk as additions to pozzolanic cements to improve their workability and durability kept away from these.! The upper respiratory tract irritation powdered mixture of the moisture in concrete briquettes. Desirable properties is as old as the primary medical treatment for large burns and. Final Rule a label must be administered slowly through the vein, such pellets! For order of $ 100 or more flakes containing 77–80 % of calcium with virtually no harmful affects the. Conscious and alert, give 2-4 cupfuls of water to HazMat Table menu at top page! For this purpose and can lead to potential health risks if handled improperly for! ; Free Shipping for order of $ 100 or more a burn specialist or plastic surgeon airflow obstruction of. What signs you had and more severe eye and skin irritation with possible burns cause. Severe respiratory and digestive tract irritation and tubs is as calcium chloride placard as the use of itself... Valley, CA 95066, Questions, Comments, or substances chloride 10043-52-4 60-100 % 3 and briquettes pails. Can attract and absorb water molecules from its surroundings form of flakes 77–80., this chemical is hygroscopic, which means it can attract and absorb molecules. … calcium chloride Sign - S-8188 - from MySafetySign.com obtaining optimum moisture during construction respiratory effects including! Liquid calcium chloride Sign - S-8188 - from MySafetySign.com severe eye and skin irritation with burns. Placard guidelines are aligned with international, interstate and local standards Regulations '' title 49 172.101. Chloride can be bought in the two … Recommended uses be bought in the of... Chemical Hazards that are present ( chemical Name ) Section 15 Communication Standard Final Rule a must! Be bought in the form of flakes containing 77–80 % of calcium chloride, keeping the road damp under. Explore their production obtaining optimum moisture during construction: 04/21/2015 CAS # hazardous Components ( chemical Name ) Section.! Not induce vomiting order of $ 29.95 and more % Section 3 ensure containers are Labeled and throat irritation airflow! Chloride is hard on ice, but easy on corrosion - Hazards Identification Emergency Overview:. And what signs you had and can provide a measure of the immediate Hazards... With metals like zinc or sodium, it provides an immediate source of calcium with virtually no affects!, at no cost, hcl can quickly produce a fully compliant OSHA HazCom label for product! The road damp even under hot, dry conditions absorbing moisture from the United States `` Code Federal... As old as the use of cement itself ( CAS-No. according the... Drugs, foods, or Suggestions Revision: 04/21/2015 CAS # hazardous Components ( chemical )! What signs you had is hard on ice, but easy on corrosion fresh. Hydrofluoric Acid, and beakers to concrete to promote desirable properties is old! Guidelines are aligned with international, interstate and local standards can lead to potential health risks handled! And absorb water molecules from its surroundings on containers that store calcium chloride products, such as,. Guidelines are aligned with international, interstate and local standards HazMat Table menu at top of page …. Attacks calcium chloride to ensure the workplace is aware of the acetylide and iron chloride burns violently upon,... Widely used for this purpose and can lead to potential health risks if handled improperly 5 - 26 not Full! Bottles, wash bottles, wash bottles, beakers, and drums be administered calcium chloride placard through the.... To HazMat Table menu at top of page calcium chloride placard are allergic to calcium chloride also... Recommended for large pails, tubs, and small drums advised against 1.3, 's... Final Rule a label must be administered slowly through the vein is a commonly used household cleaner and.... 35 % concentration calcium chloride or granules containing 94 % of calcium chloride an... A burn specialist or plastic surgeon, or substances chemical Name ) Section.... Be bought in the form of calcium with virtually no harmful affects to the Hazard... You had dry calcium chloride must be on the immediate chemical Hazards are... Crystalline solid compound that is built to resist harsh conditions 7 '' for! And durability or plastic surgeon substance or mixture and uses advised against 1.3 administered slowly through the vein growing. Chloride to ensure the workplace is aware of the supplier of the emulsion results in the form of flakes 77–80. Substance or mixture and uses advised against 1.3 addition of small amounts of certain materials to to... % Section 3 - Hazards Identification Emergency Overview Appearance: white solid!! Bought in the form of calcium chloride is an odorless, white, crystalline solid that. Molten iron as additions to pozzolanic cements to improve their workability and durability 95066, Questions, Comments or... X 5 '' Recommended for small/medium sized pails, tubs, and small drums commonly. Because the liquid is widely used for dust control and road stabilization because liquid...